PREPARATION AND CRYSTAL-STRUCTURE OF NA3SBO(PO4)2

被引：14

作者：

GUYOMARD, D

PAGNOUX, C

LETHO, JJZ

VERBAERE, A

PIFFARD, Y

机构：

[1] UNIV NANTES,CHIM SOLIDES LAB,CNRS,UMR 110,F-44072 NANTES,FRANCE

[2] FAC SCI & TECH,CHIM MINERAL LAB,ABIDJAN 22,COTE IVOIRE

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1991年 / 90卷 / 02期

关键词：

D O I：

10.1016/0022-4596(91)90154-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single phase compound Na3SbO(PO4)2 was prepared by a solid state reaction. It crystallizes in the orthorhombic system, space group P212121 with a = 6.964(1) Å, b = 9.284(2) Å, c = 12.425(2) Å, Z = 4. The structure was determined from 968 reflections collected on a Nonius CAD4 automatic diffractometer with MoKα radiation. The final R index and weighted Rw index are 0.031 and 0.039, respectively. The structure is built up from strings of corner-sharing SbO6 octahedra to which phosphate groups are linked by two of their vertices. These chains, running parallel to the a-axis, are separated from each other by sodium atoms. © 1991.

引用

页码：367 / 372

页数：6

共 9 条

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