FORMATION OF INTERCALATION COMPOUNDS OF A LAYERED SODIUM OCTOSILICATE WITH N-ALKYLTRIMETHYLAMMONIUM IONS AND THE APPLICATION TO ORGANIC DERIVATIZATION

被引：62

作者：

ENDO, K ^{[1
]}

SUGAHARA, Y ^{[1
]}

KURODA, K ^{[1
]}

机构：

[1] WASEDA UNIV, SCH SCI & ENGN, DEPT APPL CHEM, SHINJUKU KU, TOKYO 169, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 12期

关键词：

D O I：

10.1246/bcsj.67.3352

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, n-alkyltrimethylammonium ions ([CnH2n+N-1(CH3)(3)](+); n=12, 14, 16, 18) were intercalated in the interlayer space of layered sodium octosilicate (Na2Si8O17.nH(2)O) via an ion-exchange reaction. The interlayer space was further modified by grafting of the trimethylsilyl groups via a reaction between a dodecyltrimethylammonium-octosilicate intercalation compound and chlorotrimethylsilane.

引用

页码：3352 / 3355

页数：4

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