SODIUM AND POTASSIUM FLUOROSILYLAMIDES - SYNTHESIS AND CRYSTAL-STRUCTURES

被引：14

作者：

PIEPER, U ^{[1
]}

STALKE, D ^{[1
]}

VOLLBRECHT, S ^{[1
]}

KLINGEBIEL, U ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 05期

关键词：

Fluorosilylamides of K; Na;

D O I：

10.1002/cber.19901230516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium and Potassium Fluorosilylamides – Synthesis and Crystal Structures tert‐Butyl(di‐tert‐butylfluorosilyl)amine (1) reacts with sodium or potassium to give the alkali salts 2 or 3, respectively. 2 and 3 crystallize as THF adducts and form head‐to‐tail dimers. Sodium is tetracoordinated in 2 and potassium hexacoordinated in 3. The crystal structures of the alkali salts are discussed. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1039 / 1041

页数：3

共 9 条

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