A CATALYTIC ENANTIOSELECTIVE REACTION USING A C-2-SYMMETRICAL DISULFONAMIDE AS A CHIRAL LIGAND - SIMMONS-SMITH CYCLOPROPANATION OF ALLYLIC ALCOHOLS BY THE ET(2)ZN-CH2I2-DISULFONAMIDE SYSTEM

被引：78

作者：

TAKAHASHI, H

YOSHIOKA, M

SHIBASAKI, M

OHNO, M

IMAI, N

KOBAYASHI, S

机构：

[1] SAGAMI CHEM RES CTR,SAGAMIHARA,KANAGAWA 229,JAPAN

[2] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON | 1995年 / 51卷 / 44期

关键词：

D O I：

10.1016/0040-4020(95)00760-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic and enantioselective Simmons-Smith cyclopropanation of an allylic alcohol was developed by the reaction of an allylic alcohol with Et(2)Zn and CH2I2 in the presence of a catalytic amount of chiral disulfonamide 4.

引用

页码：12013 / 12026

页数：14

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