STEREOSELECTIVE PREPARATION OF A RIGID TRIMETHYLENEMETHANE COMPLEX BY REACTION OF ALLENE WITH AN IRIDIUM METHYLIDENE DERIVATIVE - X-RAY CRYSTAL-STRUCTURE OF FAC-IR[ETA-4-C(CH2)3][N(SIME2CH2PPH2)2]

被引:9
作者
FRYZUK, MD
JOSHI, K
RETTIG, SJ
机构
关键词
D O I
10.1021/om00051a071
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The trimethylenemethane complex fac-Ir[eta-4-C(CH2)3][N(SiMe2CH2PPh2)2] was prepared from the reaction of the methylidene derivative Ir = CH2[N(SiMe2CH2PPh2)2] with allene.
引用
收藏
页码:1642 / 1644
页数:3
相关论文
共 16 条
[1]  
[Anonymous], 1974, INT TABLES XRAY CRYS, VIV, p[99, 149]
[2]   ORGANIC SYNTHESES VIA TRANSITION-METAL COMPLEXES .36. MONOFUNCTIONAL TRI(METHYLENE)METHANE CHROMIUM AND IRON COMPLEXES BY ADDITION OF ALLENES TO M = C BONDS OF CARBENE COMPLEXES [J].
AUMANN, R ;
TRENTMANN, B .
CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (10) :1977-1982
[5]   TRIMETHYLENEMETHANE - EXPERIMENTAL DEMONSTRATION THAT TRIPLET-STATE IS GROUND-STATE [J].
BASEMAN, RJ ;
PRATT, DW ;
CHOW, M ;
DOWD, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (18) :5726-5727
[6]   TRIMETHYLENEMETHANEIRON TRICARBONYL [J].
EMERSON, GF ;
EHRLICH, K ;
GIERING, WP ;
LAUTERBU.PC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (13) :3172-&
[7]   SYNTHESIS OF TRIMETHYLENEMETHANE BY COMBINATION OF METHYLENE WITH ALLENE AT A DIRUTHENIUM CENTER - X-RAY STRUCTURE OF [RU2(CO)(MU-CO)(MU-ETA-1,ETA-3-CH2C(CH2)2)(ETA-C5H5)2] [J].
FILDES, MJ ;
KNOX, SAR ;
ORPEN, AG ;
TURNER, ML ;
YATES, MI .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (21) :1680-1682
[8]   SYNTHESIS AND CHARACTERIZATION OF IR(ETA-4-C4H6)[N(SIME2CH2PPH2)2] - A NON-FLUXIONAL 5-COORDINATE IRIDIUM(I) COMPLEX CONTAINING AN ETA-4-BUTADIENE LIGAND [J].
FRYZUK, MD ;
JOSHI, K ;
RETTIG, SJ .
POLYHEDRON, 1989, 8 (18) :2291-2297
[9]   THERMAL AND PHOTOCHEMICAL REARRANGEMENTS OF METHYLIRIDIUM PHOSPHIDO COMPLEXES - FORMATION OF A CYCLOMETALATED HYDRIDE BY ALPHA-ABSTRACTION OF A COORDINATED ALKYL LIGAND [J].
FRYZUK, MD ;
JOSHI, K ;
CHADHA, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) :4498-4500
[10]   PHOTOINDUCED ALPHA-HYDROGEN ELIMINATION OF AN IRIDIUM(III) DIALKYL - FORMATION OF AN ISOLABLE IRIDIUM METHYLIDENE [J].
FRYZUK, MD ;
MACNEIL, PA ;
RETTIG, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6708-6710