REDOX REACTIONS OF AN MO(V) TETRASULFOPHTHALOCYANINE

被引：9

作者：

FERRAUDI, G ^{[1
]}

NYOKONG, T ^{[1
]}

FELIZ, M ^{[1
]}

PERKOVIC, M ^{[1
]}

RILLEMA, DP ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHARLOTTE,NC 28223

来源：

INORGANICA CHIMICA ACTA | 1994年 / 215卷 / 1-2期

关键词：

ELECTROCHEMISTRY; MOLYBDENUM COMPLEXES; MACROCYCLIC LIGAND COMPLEXES; PHTHALOCYANINE COMPLEXES;

D O I：

10.1016/0020-1693(93)03664-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of an Mo(V) tetrasulfophthalocyanine and some of its thermal and photochemical reactions have been investigated in this work. Electrochemical processes have been followed by means of the UV-Vis spectral changes and compared with those observed in flash photolysis. Mo(IV) and Mo(V)-ligand-radical species are common intermediates of the electrochemical and photochemical reactions. In 254 nm irradiations of the Mo(V) tetrasulfophthalocyanine in aqueous solutions of 2-propanol, the macrocycle can be photohydrogenated and the product of the photolysis can be reoxidized with O-2 back to the parent complex.

引用

页码：27 / 32

页数：6

共 20 条

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