THEORY OF FIELD-FLOW FRACTIONATION WITH THE REVERSIBLE ADSORPTION ON CHANNEL WALLS

被引：9

作者：

ANDREEV, VP

STEFANOVICH, LA

机构：

[1] Institute for Analytical Instrumentation, Academy of Sciences, St. Petersburg, 198103

来源：

CHROMATOGRAPHIA | 1993年 / 37卷 / 5-6期

关键词：

FIELD-FLOW FRACTIONATION; REVERSIBLE ADSORPTION; PEAK BROADENING; PEAK ASYMMETRY; MATHEMATICAL MODEL;

D O I：

10.1007/BF02278642

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The particle-wall interactions in field-flow fractionating channels are described phenomenologically using the distribution coefficient, k. The time dependencies of the first and second dispersion coefficients are calculated and compared with the known solutions for the case of no adsorption. The results for the retention ratio and peak broadening are compared with the known experimental work. The model predicts the increase of peak broadening with the growth of particle-wall interactions that is consistent with the experimental data. The dependence of peak asymmetry on transverse Pe number and distribution coefficient is studied.

引用

页码：325 / 328

页数：4

共 4 条

[1]

ANDREEV VP, 1991, NAUCHNOYE PRIBOROSTR, V1, P53

[2] FLOW FIELD-FLOW FRACTIONATION - NEW METHOD FOR SEPARATING, PURIFYING, AND CHARACTERIZING DIFFUSIVITY OF VIRUSES [J].