A STEREOCONTROLLED SYNTHESIS OF PROTO-QUERCITOL

被引：10

作者：

CAMBIE, RC ^{[1
]}

RENNER, ND ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 09期

关键词：

D O I：

10.1071/CH9901597

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conduritol A tetramethyl ether (2) has been converted by hydroboration-oxidation into proto-quercitol tetramethyl ether (5) which on demethylation afforded a mixture (2:1) of proto-quercitol (4) and vibo-quercitol (11). proto-Quercitol was also obtained (15%) from conduritol A tetrabenzoate (3) by a similar sequence. © 1990 ASEG.

引用

页码：1597 / 1602

页数：6

共 7 条

[1] CYCLITOLS .15. A STEREOSPECIFIC EPIMERIZATION OF CYCLITOLS - CONFORMATIONAL FREE ENERGIES
ANGYAL, SJ
GORIN, PAJ
PITMAN, ME
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (MAR): : 1807 - &
[2] Buckingham J., 1996, DICT ORGANIC COMPOUN
[3] AN IMPROVED SYNTHESIS OF CONDURITOL-A
CAMBIE, RC
RENNER, ND
RUTLEDGE, PS
WOODGATE, PD
[J]. SYNTHETIC COMMUNICATIONS, 1989, 19 (3-4) : 537 - 546
[4] CRAGG GML, 1973, ORGANOBORANES ORGANI, pCH5
[5] DURHAM LJ, 1968, J ORG CHEM, V33, P4220
[6] FRICKE W, 1940, ARCH PHARM BER DTSCH, V278, P145
[7] HICKMANN J, 1968, J AM CHEM SOC, V90, P4445

← 1 →