CRYSTALLOGRAPHIC COMPARISON OF MONOCATIONS OF BIS(FULVALENE) IRON COBALT WITH AN IDENTICAL COUNTERION, PF6(-)

被引：7

作者：

BRUGGELLER, P ^{[1
]}

JAITNER, P ^{[1
]}

SCHOTTENBERGER, H ^{[1
]}

SCHWARZHANS, KE ^{[1
]}

机构：

[1] UNIV INNSBRUCK,INST ANORGAN & ANALYT CHEM,INNRAIN 52A,A-6020 INNSBRUCK,AUSTRIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 417卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80206-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A crystallographical comparison of bis(fulvalene)diiron (BFFeFe+) and bis(fulvalene)iron-cobalt (BFFeCo+)mono-hexafluorophosphates reveals strikingly similar lattices. This provides further evidence for a valence averaged system also in the case of the mixed membered [0.0]metallocenophane salt BFFeCo+PF6-. Despite the nearly uniform charge distribution over both metallocene units, the heteronuclear BFFeCo+ molecules are not randomly oriented in the counter-ion environment. Lattice layers are slightly displaced in contrast to BFFeFe+PF6-. The Fe-Fe and the Fe-Co compound crystallize in the monoclinic space groups C2/m and C2/c, respectively.

引用

页码：C53 / C58

页数：6

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