MONOMERIC COMPLEXES OF VANADIUM(III) AND VANADIUM(IV) WITH THE LIGANDS 1,4,7-TRIAZACYCLONONANE (L) AND 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE (L') - THE CRYSTAL-STRUCTURES OF [L'VF3].4H2O AND [L'V(ACAC)O](CLO4)

被引：16

作者：

KNOPP, P ^{[1
]}

WIEGHARDT, K ^{[1
]}

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,W-4630 BOCHUM,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 08期

关键词：

MONOMERIC VANADIUM(III) AND VANADIUM(IV) COMPLEXES; SYNTHESIS; ELECTROCHEMISTRY; X-RAY;

D O I：

10.1515/znb-1991-0817

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of monomeric complexes of V(III) and V(IV) containing the ligands 1,4,7-triazacyclononane (L) and its N-methylated derivative L' are reported: [LVF3].0,5H2O; [L'VF3].4H2O; [L'V(acac)Cl]PF6; [LVOF2].2H2O; [L'VO(acac)](ClO4). The crystal structures of [L'VF3].4H2O and of [L'VO(acac)](ClO4) have been determined by X-ray crystallography. Electronic spectra, magnetic properties and the electrochemistry of these complexes are reported.

引用

页码：1077 / 1084

页数：8

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