A CONVENIENT STEREOSELECTIVE SYNTHESIS OF CONJUGATED (2Z)-EN-4-YNOIC AND (2Z,4Z)-DIENOIC AND (2Z,4E)-DIENOIC ACID-DERIVATIVES FROM PROPIOLIC ACID-DERIVATIVES

被引：36

作者：

LU, XY

HUANG, XL

MA, SM

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)92235-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalysed one-pot sequential reaction of propiolic acid derivatives with lithium halides first and then with terminal alkynes or alkenes affords conjugated (2Z)-en-4-ynoic and (2Z,4Z)- and (2Z,4E)- dienoic acid derivatives with high stereoselectivity.

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页码：2535 / 2538

页数：4

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