THE ELECTROCHEMICAL REACTION OF SULFUR-OXYGEN COMPOUNDS .2. VOLTAMMETRIC INVESTIGATION PERFORMED ON PLATINUM

被引：32

作者：

HEMMINGSEN, T ^{[1
]}

机构：

[1] TECH UNIV DENMARK,DEPT MET,DK-2800 LYNGBY,DENMARK

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 15期

关键词：

SULFUR AND SULFUR OXYGEN COMPOUNDS; CYCLIC VOLTAMMETRY; PLATINUM;

D O I：

10.1016/0013-4686(92)85207-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The behaviour of the anions sulphide, thiosulphate, sulphite, dithionite and sulphate is examined on platinum using a triangular sweep technique. All sulphur anions, except for the sulphate anions, adsorb strongly to the platinum surface and prevent adsorbed hydrogen from being oxidized. The electrochemical behaviour of the anions on a platinum electrode may provide a method for analysing these compounds qualitatively and quantitatively.

引用

页码：2785 / 2790

页数：6

共 20 条

[1]

Chang CK, 1985, J PET TECH SEP, P1689

[2]

COSTELLO JA, 1974, S AFR J SCI, V70, P202

[3] CARBONIC-ACID CORROSION OF STEEL [J].