THE ELECTRONIC-STRUCTURE OF BA7GA4SB9, A COMPOUND SEEMINGLY PROBING THE LIMITS OF THE ZINTL CONCEPT

被引：24

作者：

ALEMANY, P ^{[1
]}

ALVAREZ, S ^{[1
]}

HOFFMANN, R ^{[1
]}

机构：

[1] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 17期

关键词：

D O I：

10.1021/ic00342a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In Ba7Ga4Sb9, a recently synthesized compound, there is a Ga4Sb,14- two-dimensional net that probes the limits of the Zintl concept. It is made up of one-dimensional alternating four- and eight-membered Ga-Sb rings, linked together into a two-dimensional structure by long but bonding Sb-Sb contacts. Band calculations reveal quite localized bonding and a half-filled Sb-Sb σ* band. A pairing distortion is indicated and should be sought experimentally. © 1990, American Chemical Society. All rights reserved.

引用

页码：3070 / 3073

页数：4

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