ELECTRICAL-PROPERTIES OF RARE-EARTH BISPHTHALOCYANINE AND BISNAPHTHALOCYANINE COMPLEXES

被引：115

作者：

BOUVET, M

SIMON, J

机构：

[1] ESPCI-CNRS, Laboratoire de Chimie et Electrochimie des Matériaux Moléculaires, 75231 Paris Cedex 05, 10, rue Vauquelin

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 172卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(90)85407-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

The electrical properties of thin film of bisphthalocyanine complexes of lutetium (Pc2Lu) and thulium (Pc2Tm) and of mixed phthalo-naphthalocyanine of lutetium (NPcPcLu) are determined as a function of the voltage and temperature. The chemical mechanisms associated with charge transport are explicated. Pc2Lu and NPcPcLu are intrinsic semiconductors whose activation energy is directly correlated to the electrochemical properties of the molecular unit in solution. Pc2Tm thin film contains traps approximately 0.17 eV above the valence level. © 1990.

引用

页码：299 / 302

页数：4

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