SPIN EFFECTS ON SPUR KINETICS - ANALYTIC MODELS FOR SINGLE-SPECIES SPURS

被引：12

作者：

GREEN, NJB ^{[1
]}

PIMBLOTT, SM ^{[1
]}

BROCKLEHURST, B ^{[1
]}

机构：

[1] UNIV NOTRE DAME,RADIAT LAB,NOTRE DAME,IN 46556

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 15期

关键词：

D O I：

10.1039/ft9918702427

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The significance of spin effects upon the kinetics of radical species in radiation-induced spurs has been studied using a prototypical single species system and several limiting models for spin effects. If the initial spin correlation is retained and the spurs remain singlet overall, the extent of reaction depends upon the spin model used. Spurs with one through six pairs of radicals are examined: the discrepancies between the predictions of the different models decrease with the number of pairs, but the effect of spin correlation remains significant.

引用

页码：2427 / 2431

页数：5

共 30 条

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