PROTON-EXCHANGE OF PRO-S HYDROGEN AT C-1 IN DIHYDROXYACETONE PHOSPHATE, D-FRUCTOSE 1,6-BISPHOSPHATE AND D-FRUCTOSE 1-PHOSPHATE CATALYZED BY RABBIT-MUSCLE ALDOLASE

被引：13

作者：

LOWE, G ^{[1
]}

PRATT, RF ^{[1
]}

机构：

[1] UNIV OXFORD, DYSON PERRINS LAB, OXFORD OX1 3QY, ENGLAND

来源：

EUROPEAN JOURNAL OF BIOCHEMISTRY | 1976年 / 66卷 / 01期

关键词：

D O I：

10.1111/j.1432-1033.1976.tb10429.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Rabbit muscle aldolase catalyses the stereospecific exchange of the pro-S C-1 H of dihydroxyacetone phosphate, D-fructose 1,6-bisphosphate and D-fructose 1-phosphate. The deuteration of the substrates in 2H2O was followed by 1H NMR spectroscopy. The rate of exchange is at least 400 times slower than the H+ exchange of the pro-S H at C-3 in dihydroxyacetone phosphate.

引用

页码：95 / 104

页数：10

共 33 条

[1] QUANTITATIVE DETERMINATION OF MONONUCLEOTIDE CONFORMATIONS IN SOLUTION USING LANTHANIDE ION SHIFT AND BROADENING NMR PROBES [J].

BARRY, CD ;

NORTH, ACT ;

GLASEL, JA ;

WILLIAMS, RJP ;

XAVIER, AV .

NATURE, 1971, 232 (5308) :236-+

[2] RATES OF IONISATION AND ENOLISATION OF SOME ALIPHATIC KETONES [J].

BELL, RP ;

HILLIER, GR ;

MANSFIEL.JW ;

STREET, DG .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1967, (08) :827-&

[3] INTRAMOLECULAR AND INTERMOLECULAR CATALYSIS IN IODINATION OF 4-DIETHYLAMINOBUTAN-2-ONE AND 5-DIETHYLAMINOPENTAN-2-ONE [J].

BELL, RP ;

TIMIMI, BA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1973, (11) :1518-1521

[4] KETIMINE INTERMEDIATES IN AMINE-CATALYZED ENOLIZATION OF ACETONE [J].

BENDER, ML ;

WILLIAMS, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (11) :2502-&

[5] MAGNETIC-RESONANCE STUDIES OF ANOMERIC DISTRIBUTION AND MANGANESE BINDING PROPERTIES OF FRUCTOSE PHOSPHATES [J].

BENKOVIC, SJ ;

MILDVAN, AS ;

ENGLE, JL .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1972, 47 (04) :852-&

[6] MECHANISM OF ACTION OF ALDOLASE AND PHOSPHOTRIOSE ISOMERASE [J].

BLOOM, B ;

TOPPER, YJ .

SCIENCE, 1956, 124 (3229) :982-983

[7] BIOCHEMICAL IMPORTANCE OF BINDING OF PHOSPHATE BY ARGINYL GROUPS - MODEL COMPOUNDS CONTAINING METHYLGUANIDINIUM ION [J].

COTTON, FA ;

HAZEN, EE ;

DAY, VW ;

LARSEN, S ;

NORMAN, JG ;

WONG, STK ;

JOHNSON, KH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (07) :2367-2369

[8] COMPARATIVE STUDY OF ALDOLASE FROM HUMAN MUSCLE AND LIVER [J].

EAGLES, PAM ;

IQBAL, M .

BIOCHEMICAL JOURNAL, 1973, 133 (03) :429-+

[9] TEMPERATURE DEPENDENCE OF DELTAPD CORRECTION FOR USE OF GLASS ELECTRODE IN D2O [J].

FIFE, TH ;

BRUICE, TC .

JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (06) :1079-&

[10]

GRACY RW, 1968, J BIOL CHEM, V243, P5410

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