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EFFECT OF AMINE SUBSTITUENTS AND NEUTRAL LEAVING GROUPS ON THE ACTIVATION VOLUME FOR AQUATION OF OCTAHEDRAL PENTAAMINE COMPLEXES OF CR-III AND RH-III
被引：16
作者：
GONZALEZ, G
MARTINEZ, M
RODRIGUEZ, E
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
|
1995年
/
05期
关键词：
D O I：
10.1039/dt9950000891
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
The activation volumes were obtained for the aquation reactions of [M(RNH(2))(5)L](3+) (M = Cr, R = Me, L = Me(2)SO, HCONMe(2) or MeCONMe(2) M = Rh, R = H or Me, L = Me(2)SO or HCONMe(2)); they are in accord with the existence of a dissociative shift in the substitution mechanism; not only with the size of the substituent R, but also with the size of the leaving ligands L.
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页码：891 / 892
页数：2
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