SYNTHESIS, STRUCTURE, AND REACTIONS OF A 10-SB-4 TYPE ANTIMONY ATE COMPLEX

被引：25

作者：

AKIBA, K

NAKATA, H

YAMAMOTO, Y

KOJIMA, S

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 08期

关键词：

D O I：

10.1246/cl.1992.1559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 10-Sb-4 type organoantimony ate complex was prepared from hexafluorocumyl alcohol and SbCl3 as an air and water stable compound. Its X-ray structural analysis revealed a distorted pseudo-trigonal bipyamidal structure. The compound reacted with both alkyl halides and organolithium reagents to yield neutral 10-Sb-5 compounds.

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页码：1559 / 1562

页数：4

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