MECHANISM OF CARBON NITROGEN BOND-CLEAVAGE DURING AMYLAMINE HYDRODENITROGENATION OVER A SULFIDED NIMO/AL2O3 CATALYST

被引：32

作者：

PORTEFAIX, JL

CATTENOT, M

GUERRICHE, M

BREYSSE, M

机构：

[1] Institut de Recherches sur la Catalyse, Laboratoire Propre, du C.N.R.S. conventionné à l'Université Claude Bernard-Lyon I, Villeurbanne cédex, 69626

来源：

CATALYSIS LETTERS | 1991年 / 9卷 / 1-2期

关键词：

AMYLAMINE HYDRODENITROGENATION; C-N BOND CLEAVAGE MECHANISM; HYDROTREATING CATALYSTS;

D O I：

10.1007/BF00769091

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By comparison of the hydrodenitrogenation rate of amylamine with those of neopentylamine and tert-amylamine over a conventional catalyst, it was evidenced that the hydrogen atoms of the carbon in the beta position with respect to the nitrogen atom participate in the C-N bond cleavage. A detailed mechanism including the interaction with the catalyst is proposed for this reaction.

引用

页码：127 / 132

页数：6