(HE,H2+) DYNAMICS REVISITED

被引：27

作者：

KUMAR, S ^{[1
]}

SATHYAMURTHY, N ^{[1
]}

BHALLA, KC ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV CHEM,BOMBAY 400085,INDIA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 06期

关键词：

D O I：

10.1063/1.464972

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The differential cross section for the backward and the forward scattering of the product in (He,H2+) collisions and its dependence on reagent vibration and translation as determined by a three dimensional quasiclassical trajectory study are shown to be in accord with the recently reported experimental results. An investigation of the role of reagent rotation on the differential and integral cross sections for the reaction He + H-2+ --> HeH+ + H and also on the branching ratio for the two isotopic channels in He + HD+ --> HeH+ + D; HeD+ + H reveals that the dynamical attributes are not strongly dependent on the initial rotational state of the diatom as there is no preferred geometry for the reaction.

引用

页码：4680 / 4689

页数：10

共 74 条

[1]

ACHTENHAGEN M, COMMUNICATION

[2] DYNAMICS OF HEAVY + LIGHT-HEAVY ATOM TRANSFER-REACTIONS THE REACTION CL+HCL-]CLH+CL [J].