AN EXPERIMENTAL-DETERMINATION OF THE HEAT OF FORMATION OF C2 AND THE C-H BOND-DISSOCIATION ENERGY IN C2H

被引：114

作者：

URDAHL, RS

BAO, YH

JACKSON, WM

机构：

[1] Department of Chemistry, University of California, Davis

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 178卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(91)90276-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotational cutoff levels of C2(B' 1-SIGMA-g+, v" = 1,2), produced in the multiphoton dissociation of jet-cooled acetylene at 193 nm, have been measured using laser-induced fluorescence. This data is used to calculate the values DELTA-H(f,0)(C2) = 194.8 +/- 0.5 kcal/mol and D0(CC-H) = 112.0 +/- 0.8 kcal/mol, in excellent agreement with the latest theoretical calculations.

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页码：425 / 428

页数：4

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