SELECTIVE OXIDATION OF OPTICALLY-ACTIVE SEC,SEC-1,2-DIOLS BY DIOXIRANES - A PRACTICAL METHOD FOR THE SYNTHESIS OF HOMOCHIRAL ALPHA-HYDROXY KETONES IN HIGH OPTICAL PURITY

被引：49

作者：

D'ACCOLTI, L ^{[1
]}

DETOMASO, A ^{[1
]}

FUSCO, C ^{[1
]}

ROSA, A ^{[1
]}

CURCI, R ^{[1
]}

机构：

[1] UNIV BARI, CNR, CTR MISO, DEPT CHEM, V AMENDOLA 173, I-70126 BARI, ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 14期

关键词：

D O I：

10.1021/jo00066a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By employing either dimethyldioxirane or its trifluoromethyl analog, the direct, high-yield conversion of one cyclic and three open chain optically sec,sec-1,2-diols to the corresponding alpha-hydroxy ketones in high optical yield has been achieved.

引用

页码：3600 / 3601

页数：2

共 48 条

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