SYNTHESIS OF LOW-SPIN [MNII(L2)2]I2.2MEOH AND [CUIII(L1)] VIA CONDENSATION OF S-METHYLISOTHIOSEMICARBAZIDE AND PENTANE-2,4-DIONE IN THE PRESENCE OF AIR

被引：43

作者：

KNOF, U ^{[1
]}

WEYHERMULLER, T ^{[1
]}

WOLTER, T ^{[1
]}

WIEGHARDT, K ^{[1
]}

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM I,W-4630 BOCHUM,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 09期

关键词：

D O I：

10.1039/c39930000726

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [MnII(L2)2]I2.2MeOH 1 and [CuIII(L1)] 2 have been synthesized by a template-like reaction between S-methylisothiosemicarbazide and pentane-2,4-dione, with MnCl2 and Cu2(MeCO2)4.2H2O, respectively, in MeOH by air oxidation; both species have been characterized by X-ray crystallography.

引用

页码：726 / 728

页数：3

共 13 条

[1] LOW-SPIN TRIS(QUINONE OXIMATES) OF MANGANESE(II,III) - SYNTHESIS, ISOMERISM, AND EQUILIBRIA [J].

BASU, P ;

CHAKRAVORTY, A .

INORGANIC CHEMISTRY, 1992, 31 (24) :4980-4986

[2]

BASU P, 1988, INORG CHEM, V27, P1850

[3] LIGAND EFFECTS ON THERMODYNAMIC STABILIZATION OF COPPER(III)-PEPTIDE COMPLEXES [J].

BOSSU, FP ;

CHELLAPPA, KL ;

MARGERUM, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) :2195-2203

[4] SYNTHESIS AND STRUCTURE OF A TRINUCLEAR MANGANESE(II) COMPLEX CONTAINING LOW-SPIN METAL [J].

CHATTOPADHYAY, S ;

BASU, P ;

PAL, S ;

CHAKRAVORTY, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (12) :3829-3833

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF THE COPPER(III)-TRIPEPTIDE COMPLEX OF TRI-ALPHA-AMINOISOBUTYRIC ACID [J].

DIADDARIO, LL ;

ROBINSON, WR ;

MARGERUM, DW .

INORGANIC CHEMISTRY, 1983, 22 (07) :1021-1025

[6] Information on tetrazole. [J].

Freund, M ;

Paradies, T .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1901, 34 :3110-3122

[7] TRANSITION-METAL COMPLEXES WITH THIOSEMICARBAZIDE-BASED LIGANDS .14. IRON(IV) COMPLEXES WITH 2,4-PENTANEDIONE BIS(S-ALKYLISOTHIOSEMICARBAZONE) - CRYSTAL AND MOLECULAR-STRUCTURE OF IODO(2,4-PENTANEDIONE BIS(S-ETHYLISOTHIOSEMICARBAZONATO)(3-))IRON(IV) [J].

GERBELEU, NV ;

SIMONOV, YA ;

ARION, VB ;

LEOVAC, VM ;

TURTA, KI ;

INDRICHAN, KM ;

GRADINARU, DI ;

ZAVODNIK, VE ;

MALINOVSKII, TI .

INORGANIC CHEMISTRY, 1992, 31 (15) :3264-3268

[8]

GERBELEU NV, 1985, ZH NEORG KHIM+, V30, P2833

[9] X-RAY-DIFFRACTION ANALYSIS AND IR-SPECTROSCOPY OF THE STRUCTURE OF HEXAAMINEDIIODIDES, [M(NH3)6]I2, FROM IRON AND MANGANESE [J].

JACOBS, H ;

BOCK, J ;

STUVE, C .

JOURNAL OF THE LESS-COMMON METALS, 1987, 134 (02) :207-214

[10] TRANSITION-METAL COMPLEXES WITH THE THIOSEMICARBAZIDE-BASED LIGANDS .16. NOVEL IRON(IV) COMPLEXES WITH PENTANE-2,4-DIONE BIS(S-METHYLISOTHIOSEMICARBAZONE) [J].

LEOVAC, VM ;

JOVANOVIC, LS ;

CESLJEVIC, VI ;

BJELICA, LJ ;

EVIC, NJ .

POLYHEDRON, 1992, 11 (09) :1029-1035

← 1 2 →