THE REACTION OF DISILYLACETYLENES WITH CYCLOPENTADIENYL MANGANESE - FORMATION OF VINYLIDENE COMPLEXES BY 1,2-SILYL SHIFT

被引：43

作者：

SAKURAI, H

FUJII, T

SAKAMOTO, K

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 02期

关键词：

D O I：

10.1246/cl.1992.339

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both cyclic and acyclic acetylenes substituted by two silyl groups on each end undergo facile 1,2-silyl shift in the reaction with cyclopentadienyltricarbonylmanganese under photochemical conditions to give 2,2-disilylvinylidene complexes. Several interesting reactions of the novel complexes are described.

引用

页码：339 / 342

页数：4

共 7 条

[1] IRON(II) VINYLIDENES AND CHROMIUM CARBENE COMPLEXES IN BETA-LACTAM SYNTHESIS
BARRETT, AGM
MORTIER, J
SABAT, M
STURGESS, MA
[J]. ORGANOMETALLICS, 1988, 7 (12) : 2553 - 2561
[2] BRUCE MI, 1983, ADV ORGANOMET CHEM, V22, P59
[3] NESMEYANOV AN, 1975, DOKL AKAD NAUK SSSR+, V220, P105
[4] IRON CARBONYL MEDIATED INTRAMOLECULAR DIMERIZATION OF ACETYLENE TO A NOVEL (TRIMETHYLENEMETHANE) DIIRON HEXACARBONYL COMPLEX
SAKURAI, H
HIRAMA, K
NAKADAIRA, Y
KABUTO, C
[J]. CHEMISTRY LETTERS, 1988, (03) : 485 - 486
[5] COMPOUNDS OF PERSILYL SUBSTITUTED PI-ELECTRON SYSTEMS
SAKURAI, H
[J]. NIPPON KAGAKU KAISHI, 1990, (05) : 439 - 450
[6] CHEMISTRY OF ORGANOSILICON COMPOUNDS .235. A NEW MODE OF TRANSITION-METAL-CATALYZED INTRAMOLECULAR DIMERIZATION OF ALKYNES - THE 1ST SYNTHESIS OF A METHYLENECYCLOPROPENE COMPLEX
SAKURAI, H
HIRAMA, K
NAKADAIRA, Y
KABUTO, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (22) : 6880 - 6881
[7] INTRAMOLECULAR CYCLOTRIMERIZATION OF MACROCYCLIC AND ACYCLIC TRIYNES WITH GROUP-6 METAL-CARBONYLS - THE FORMATION OF FULVENE AND BENZENE
SAKURAI, H
NAKADAIRA, Y
HOSOMI, A
ERIYAMA, Y
HIRAMA, K
KABUTO, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) : 8315 - 8316

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