HOMOGENEOUS CATALYSIS - [TI(CP)2(CF3SO3)2] AND [ZR(CP)2(CF3SO3)2THF], EFFICIENT CATALYSTS FOR THE DIELS-ALDER REACTION

被引：57

作者：

HOLLIS, TK ^{[1
]}

ROBINSON, NP ^{[1
]}

BOSNICH, B ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT CHEM,5735 S ELLIS AVE,CHICAGO,IL 60637

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 08期

关键词：

D O I：

10.1021/om00044a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The readily prepared species [Ti(Cp)2-(CF3SO3)2] and [Zr(CP)2(CF3SO3)2THF] are efficient catalysts for the Diels-Alder reaction at very low catalyst loadings, giving accelerations of between 10(3) and > 10(5) over the corresponding thermal reactions.

引用

页码：2745 / 2748

页数：4

共 15 条

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