COOPERATIVITY IN RH-2 COMPLEXES - HIGH CATALYTIC ACTIVITY AND HIGH REGIOSELECTIVITY IN THE HYDROFORMYLATION OF OLEFINS

被引：51

作者：

SUSSFINK, G

机构：

[1] Institut de Chemie, Université de Neuchâtel, Neuchâtel, CH-2000

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1002/anie.199400671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A breakthrough in tailor‐made homogeneous catalysts has been achieved by Stanley et al., who synthesized the rac‐Rh2 complex 1 with a new tetraphosphane ligand, which catalyzes the hydroformylation of olefins with a high activity and extremely selectively. The combination of these important catalytic properties is traced back to the intramolecular interaction of the two Rh centers fixed by the ligand matrix. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：67 / 69

页数：3

共 11 条

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