ENZYMATIC PREPARATION OF OPTICALLY PURE TRANS-1,2-CYCLOALKANEDIOLS

被引：38

作者：

SEEMAYER, R ^{[1
]}

SCHNEIDER, MP ^{[1
]}

机构：

[1] BERG UNIV GESAMTHSCH WUPPERTAL,FB 9,W-5600 WUPPERTAL 1,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-1,2-Cycloalkanediols (R,R)- 1-4 and (S,S)-1-3 of high optical purities are prepared by enzymatic hydrolysis and esterification catalysed by a lipase from Pseudomonas sp. (SAM II).

引用

页码：49 / 50

页数：2

共 13 条

[1] QUANTITATIVE-ANALYSES OF BIOCHEMICAL KINETIC RESOLUTIONS OF ENANTIOMERS [J].

CHEN, CS ;

FUJIMOTO, Y ;

GIRDAUKAS, G ;

SIH, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7294-7299

[2] AN EFFICIENT SYNTHESIS OF BOTH ENANTIOMERS OF TRANS-1,2-CYCLOPENTANEDIOL AND THEIR CONVERSION TO 2 NOVEL BIDENTATE PHOSPHITE AND FLUOROPHOSPHINITE LIGANDS [J].

CUNNINGHAM, AF ;

KUNDIG, EP .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (08) :1823-1825

[3] ENZYMATIC-REACTIONS IN ORGANIC-SYNTHESIS .2. ESTER INTERCHANGE OF VINYL ESTERS [J].

DEGUEILCASTAING, M ;

DEJESO, B ;

DROUILLARD, S ;

MAILLARD, B .

TETRAHEDRON LETTERS, 1987, 28 (09) :953-954

[4] CHIRAL CROWN ETHERS DERIVED FROM (+)-(1S, 2S)-TRANS-CYCLOHEXANE-1,2-DIOL [J].

HAYWARD, RC ;

OVERTON, CH ;

WHITHAM, GH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1976, (22) :2413-2415

[5] ENANTIOMERICALLY PURE CYCLOHEXANOLS AND CYCLOHEXANE-1,2-DIOL DERIVATIVES - CHIRAL AUXILIARIES AND SUBSTITUTES FOR (-)-8-PHENYLMENTHOL - A FACILE ENZYMATIC ROUTE [J].

LAUMEN, K ;

BREITGOFF, D ;

SEEMAYER, R ;

SCHNEIDER, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (03) :148-150

[6] A HIGHLY SELECTIVE ESTER HYDROLASE FROM PSEUDOMONAS SP FOR THE ENZYMATIC PREPARATION OF ENANTIOMERICALLY PURE SECONDARY ALCOHOLS - CHIRAL AUXILIARIES IN ORGANIC-SYNTHESIS [J].

LAUMEN, K ;

SCHNEIDER, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (09) :598-600

[7] ENZYMIC PREPARATION OF ENANTIOMERICALLY PURE SECONDARY ALCOHOLS - ESTER SYNTHESIS BY IRREVERSIBLE ACYL TRANSFER USING A HIGHLY SELECTIVE ESTER HYDROLASE FROM PSEUDOMONAS SP - AN ATTRACTIVE ALTERNATIVE TO ESTER HYDROLYSIS [J].

LAUMEN, K ;

BREITGOFF, D ;

SCHNEIDER, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1459-1461

[8] ENZYMIC PREPARATION OF ENANTIOMERICALLY PURE CYCLOHEXANOLS - ESTER SYNTHESIS BY IRREVERSIBLE ACYL TRANSFER [J].

LAUMEN, K ;

SEEMAYER, R ;

SCHNEIDER, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (01) :49-51

[9]

LAUMEN K, 1987, THESIS BERGISCHE U

[10]

MORRISON JD, 1985, ASYMMETRIC SYNTHESIS, V5

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