FORMATION OF A CHELATING BIDENTATE NITROSOALKANE COMPLEX OF RUTHENIUM(II) THROUGH REACTION OF H2O WITH A HIGH-VALENT BIS(IMIDO)RUTHENIUM INTERMEDIATE AND X-RAY CRYSTAL-STRUCTURE OF [RU(BPY)(2)(ONCME(2)CME(2)NO)][CLO4]2-CENTER-DOT-ME(2)CO

被引：13

作者：

CHIU, WH ^{[1
]}

CHEUNG, KK ^{[1
]}

CHE, CM ^{[1
]}

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000441

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of [Ru-II(bpy)(2)(NH(2)CMe(2)CMe(2)NH(2))](2+) by Ce-IV in H2O generates the highly reactive cis-bis(imido)ruthenium(VI) intermediate, which reacts with H2O to give [Ru-II(bpy)(2)(ONCMe(2)CMe(2)NO)](2+), the structure of which has been determined by X-ray crystallography.

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页码：441 / 442

页数：2

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