TRANSPORT-PROPERTIES OF N-TYPE BI2(TE1-XSEX)3 SINGLE-CRYSTAL SOLID-SOLUTIONS (X-LESS-THAN-OR-EQUAL-TO-0.05)

被引:88
作者
CARLE, M
PIERRAT, P
LAHALLEGRAVIER, C
SCHERRER, S
SCHERRER, H
机构
[1] Laboratoire de Métallurgie Physique et Sciences des Matériaux, Ecole des Mines de Nancy, 54042 Nancy cedex, Parc de Saurupt
关键词
SEMICONDUCTORS; CHALCOGENIDES; TRANSPORT PROPERTIES; ELECTRICAL CONDUCTIVITY; THERMAL CONDUCTIVITY;
D O I
10.1016/0022-3697(94)00166-9
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Measurements of the transport properties of Bi2(Te1-xSex)3 single crystal solid solutions with x = 0.025 and x = 0.05 are described as a function of deviations from stoichiometry. From measurements of the electrical and thermal conductivities, and the Seebeck coefficient at room temperature, a maximum in the figure of merit Z = 2.9 x 10(3) K-1 was determined for the solid solution containing 2.5% Bi2Se3. Analysis of the results allows us to present the main features of the band structure and the transport properties of these solid solutions.
引用
收藏
页码:201 / 209
页数:9
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