NON-RRKM KINETICS IN GAS-PHASE SN2 NUCLEOPHILIC-SUBSTITUTION

被引：102

作者：

VANDELINDE, SR ^{[1
]}

HASE, WL ^{[1
]}

机构：

[1] WAYNE STATE UNIV,DEPT CHEM,DETROIT,MI 48202

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 16期

关键词：

D O I：

10.1021/j100379a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Classical trajectories are used to simulate the intramolecular and unimolecular dynamics of Cl-⋯CH3Cl complexes formed by collisions between Cl- and CH3Cl. Unimolecular rate constants for decomposition of the complexes are decidedly non-RRKM and are consistent with a model in which only three or fewer modes in the complex are active in intramolecular vibrational energy redistribution. © 1990 American Chemical Society.

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页码：6148 / 6150

页数：3

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