THE DIFFERENCE IN SPECIFIC-HEAT BETWEEN LIQUIDS AND SOLIDS CP (L-S) - CALCULATION OF THE GLASS TG AND JELLY TJS']JS AND TJG TRANSITION-TEMPERATURES, AND THE CALCULATION OF PHASE-DIAGRAMS

被引:2
作者
HOCH, M
机构
关键词
D O I
10.1051/jcp/1993900201
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In the present paper we summarize our results on the effect of the difference in specific heat between liquids and solids C(p)(L-s) on the calculation of phase diagrams, the calculation of the glass T(g) and ''Jelly'' T(jS) and T(JG) transition temperatures, and on the estimation of C(p)(L-s) . We treat the binary systems Ca-Al, Ca-Pb. We use the linear expression for C(p)(L-s): C(p)(L-s)/R = e + f*T, e/-f = 1.081 +/- 0.181 and e/Tmp = 7.0 +/- 4.3, Tmp the melting point expressed in kK.
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页码:201 / 208
页数:8
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