STEREOSPECIFIC SYNTHESIS OF ALPHA-C-ARYL-DELTA(2)-GLYCOPYRANOSIDES AND BETA-C-ARYL-DELTA(2)-GLYCOPYRANOSIDES FROM P-TERT-BUTYLPHENYL ALPHA-O-DELTA(2)-GLYCOPYRANOSIDE VIA GRIGNARD-REAGENTS

被引：22

作者：

MOINEAU, C ^{[1
]}

BOLITT, V ^{[1
]}

SINOU, D ^{[1
]}

机构：

[1] UNIV LYON 1,CPE LYON,URA 463,SYNTH ASYMETR LAB,F-69622 VILLEURBANNE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalysed coupling of p-tert-butylphenyl alpha-O-Delta(2)-glycopyranoside with various substituted arylmagnesium bromides provides the corresponding C-alpha-aryl-Delta(2)-glycopyranosides, while nickel-mediated reaction allows the preparation of the C-beta-aryl anomers.

引用

页码：1103 / 1104

页数：2

共 22 条

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