COMPUTER MODELING OF FRAGMENTATION PROCESSES IN RADIO-FREQUENCY MULTIPOLE COLLISION CELLS

被引：28

作者：

DAVIS, SC

WRIGHT, B

机构：

[1] Kratos Analytical, Manchester, M31 2LD, Barton Dock Road

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1990年 / 4卷 / 06期

关键词：

D O I：

10.1002/rcm.1290040605

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

To date, methods for calculating the trajectories of ions in radio frequency (RF) multipole fields have involved solving, analytically or numerically, the appropriate equations of motion. Another method is presented here whereby a non‐ideal distribution of field may be modelled and the position of an ion can be tracked, as it traverses the multipole. The validity of the calculations is discussed and some of the properties of collision cells are explained. Fragmentation processes within the cell are modelled showing that the focusing properties within the cell have a striking effect on parent‐ and daughter‐ion transmission. Copyright © 1990 John Wiley & Sons Limited

引用

页码：186 / 197

页数：12

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