GAS-PHASE ACID-INDUCED RING-OPENING OF AN ALPHA,BETA-EPOXYSILANE - THE 1ST CASE OF COMPLETE REGIOSELECTIVITY AND STEREOSELECTIVITY IN AN ION-MOLECULE REACTION IN THE GAS-PHASE

被引：8

作者：

CROTTI, P

MACCHIA, F

PIZZABIOCCA, A

RENZI, G

SPERANZA, M

机构：

[1] UNIV CAMERINO,DIPARTIMENTO SCI CHIM,I-62032 CAMERINO,ITALY

[2] CNR,IST CHIM NUCL,I-0016 MONTEROTONDO STAZ,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 06期

关键词：

D O I：

10.1039/c39860000485

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：485 / 487

页数：3

共 9 条

[1] ARE CARBENIUM IONS STABILIZED OR DESTABILIZED BY ALPHA-SILYL SUBSTITUTION - THE SOLVOLYSIS OF 2-(TRIMETHYLSILYL)-2-ADAMANTYL PARA-NITROBENZOATE [J].

APELOIG, Y ;

STANGER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (09) :2806-2807

[2]

BERTI G, 1984, J CHEM SOC PERK T 1, P1183, DOI 10.1039/p19840001183

[3]

DEVIS AP, 1981, J CHEM SOC P1, P1934

[4] ORGANOSILICON COMPOUNDS WITH FUNCTIONAL-GROUPS PROXIMATE TO SILICON .13. CLEAVAGE AND REARRANGEMENT REACTIONS OF EPOXYETHYLSILANES [J].

EISCH, JJ ;

GALLE, JE .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (15) :2615-2621

[5] NEUTRAL PRODUCTS FROM NUCLEOPHILIC-SUBSTITUTION IN THE GAS-PHASE - DISPLACEMENT OF WATER FROM PROTONATED SECONDARY ALCOHOLS [J].

HALL, DG ;

GUPTA, C ;

MORTON, TH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) :2416-2417

[6] GAS-PHASE ACID-INDUCED NUCLEOPHILIC DISPLACEMENT-REACTIONS - STEREOCHEMISTRY OF INTERMOLECULAR AND INTRAMOLECULAR SUBSTITUTIONS AT SATURATED CARBON [J].

SPERANZA, M ;

ANGELINI, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (09) :3115-3120

[7] NEW SYNTHESIS OF ALDEHYDES VIA VINYLSILANES [J].

STORK, G ;

COLVIN, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (08) :2080-&

[8] VINYLSILANES AS CARBONYL PRECURSORS - USE IN ANNELATION REACTIONS [J].

STORK, G ;

JUNG, ME .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (11) :3682-3684

[9] MAGNITUDE AND ORIGIN OF THE BETA-SILICON EFFECT ON CARBENIUM IONS [J].

WIERSCHKE, SG ;

CHANDRASEKHAR, J ;

JORGENSEN, WL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (06) :1496-1500

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