PREPARATION, STRUCTURE, PROPERTIES AND PHASE-TRANSITIONS OF NEW RADICAL CATION SALTS

被引：8

作者：

ENKELMANN, V

机构：

[1] Max-Planck-Institut für Polymerforschung

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91421-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The phase transition in FA2PF6 crystals has been investigated by X-ray structure analyses. of the two transitions which have been reported for this material the higher one with a transition temperature of 206 K is a structural phase transition of second order. The displacements of the aromatic rings and of the PF6 counterions have been determined as a function of temperature. The nature of the lower transition which is observed at 180 K is still not clear. Preliminary data suggest the existence of an incommensurate structure, probably a charge density wave.

引用

页码：2547 / 2552

页数：6

共 9 条

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