A LOCAL COMPOSITION MODEL FOR THE EXCESS GIBBS ENERGY OF AQUEOUS-ELECTROLYTE SYSTEMS

被引：824

作者：

CHEN, CC ^{[1
]}

EVANS, LB ^{[1
]}

机构：

[1] MIT,DEPT CHEM ENGN,CAMBRIDGE,MA 02139

来源：

AICHE JOURNAL | 1986年 / 32卷 / 03期

关键词：

IONS; -; SOLVENTS;

D O I：

10.1002/aic.690320311

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The electrolyte nonrandom two-liquid (NRTL) model proposed by C. C. Chen et al. is generalized to represent the excess Gibbs energy of aqueous multicomponent electrolyte systems. Using only binary parameters, the model correlates and predicts the deviation from ideality of aqueous multicomponent electrolyte systems over the entire range of temperature and concentration.

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收藏

页码：444 / 454

页数：11

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