HYDRIDE FORMATION RATES OF TITANIUM-BASED BCC SOLID-SOLUTION ALLOYS

被引：69

作者：

MAELAND, AJ

LIBOWITZ, GG

LYNCH, JF

机构：

[1] Allied Corp, Morristown, NJ, USA, Allied Corp, Morristown, NJ, USA

来源：

JOURNAL OF THE LESS-COMMON METALS | 1984年 / 104卷 / 02期

关键词：

TITANIUM COMPOUNDS;

D O I：

10.1016/0022-5088(84)90420-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Titanium has an h. c. p. structure at room temperature and reacts with hydrogen at an appreciable rate only at elevated temperatures. However, the metal undergoes an allotropic transformation to a bcc structure at 882. 5 degree C. The bcc phase can be stabilized by suitable alloying with niobium, molybdenum, vanadium etc. so that the bcc phase is retained at room temperature. Rapid reactions at room temperature of these bcc solid solution phases with hydrogen have been observed when small amounts of a third element are added. Suitable additions are those elements which have radii 5% or more smaller than that of titanium.

引用

页码：361 / 364

页数：4

共 7 条

[1]

Hansen M., 1958, J ELECTROCHEM SOC, DOI DOI 10.1149/1.2428700

[2]

LAGOS M, 1984, SURF SCI, V138, pL161, DOI 10.1016/0039-6028(84)90245-0

[3] KINETICS OF HYDROGEN ABSORPTION IN TRANSITION-METALS AND SUBSURFACE BONDING [J].

LAGOS, M ;

MARTINEZ, G ;

SCHULLER, IK .

PHYSICAL REVIEW B, 1984, 29 (10) :5979-5981

[4]

LIBOWITZ GG, 1965, SOLID STATE CHEM BIN, P66

[5] HYDRIDE FORMATION RATES OF BCC GROUP V METALS [J].

MAELAND, AJ ;

LIBOWITZ, GG ;

LYNCH, JF ;

RAK, G .

JOURNAL OF THE LESS-COMMON METALS, 1984, 104 (01) :133-139

[6]

Murray J. L., 1981, B ALLOY PHASE DIAGR, V2, P55, DOI 10.1007/BF02873704

[7]

Murray J.L., 1981, B ALLOY PHASE DIAGRA, V2, P48, DOI [10.1007/BF02873703, DOI 10.1007/BF02873703]

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