4-(1,2,4-TRIAZOLYL) CATION - POSSIBLE GENERATION AND REACTIONS

被引：4

作者：

ABRAMOVITCH, RA

BECKERT, JM

PENNINGTON, WT

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 07期

关键词：

NON-NUCLEOPHILIC MEDIA; ARYLNITRENIUM IONS; AROMATIC-SUBSTITUTION; TRIFLUOROACETIC-ACID; ALKYLNITRENIUM IONS; METHYLENE CHLORIDE; ANODIC OXIDATION; AZIDES; SALTS; ELECTROLYSIS;

D O I：

10.1039/p19910001761

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermolysis of N-(1,2,4-triazol-4-yl)-2,4,6-trimethylpyridinium tetrafluoroborate 3 in mesitylene-hexafluoroisopropyl solution gives a variety of products, but none derived from attack of the free nitrenium ion upon mesitylene; a possible explanation is a SET from trimethylpyridine to the nitrenium ion within the solvent cage.

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页码：1761 / 1762

页数：2

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