HYDROFORMYLATION OF CHIRAL TERPENES WITH PTCL(SNCL3)-(BIS-PHOSPHINE) AS CATALYST

被引：42

作者：

KOLLAR, L

BAKOS, J

HEIL, B

SANDOR, P

SZALONTAI, G

机构：

[1] HUNGARIAN ACAD SCI,CENT RES INST CHEM,H-1025 BUDAPEST,HUNGARY

[2] RES INST HEAVY CHEM IND,H-8201 VESZPREM,HUNGARY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)87153-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(+)-R-Limonene and (-)-R-carvone undergo hydroformylation in the presence of catalytic Pt-bisphosphine-SnCl2 systems to yield exclusively the linear products. The internal double bond and the carbonyl group remain intact in both substrates during the reaction. The variation of the diastereomeric composition of the aldehydes upon variation of the chelating phosphine in the catalyst has been investigated. © 1990.

引用

页码：147 / 152

页数：6

共 9 条

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