INTRAMOLECULAR BARBIER REACTION OF A 3-(3'-BROMOPROPYL) BICYCLO[2.2.2]OCT-5-EN-2-ONE

被引：4

作者：

ZHANG, W ^{[1
]}

DOWD, P ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)60354-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular Barbier reactions, initiated with lithium or magnesium metals, were carried out on a model compound 3 and afforded four products, including the cyclic product 6 and cyclopropane-containing product 7. Single and double electron transfer sequences are proposed to explain their formation.

引用

页码：2095 / 2098

页数：4

共 19 条

[1]

BECKWITH A, 1989, J AM CHEM SOC, V111, P234

[2] REACTION OF CROTYLMAGNESIUM BROMIDE WITH HINDERED KETONES . FIRST EXAMPLES OF A REVERSIBLE GRIGNARD REACTION [J].