HALF-SANDWICH COMPLEXES WITH INTRAMOLECULAR AMINO GROUP COORDINATION - SYNTHESIS AND STRUCTURE OF CATIONIC MOLYBDENUM DIENYL COMPLEXES

被引：56

作者：

WANG, TF

WEN, YS

机构：

[1] Institute of Chemistry, Academia Sinica, Taipei

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 439卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)80226-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A half-sandwich cationic molybdenum dienyl complex with intramolecular amino group coordination was obtained from eta5-C5H4CH2CH2N(CH3)2Mo(CO)2(eta3-C6H9) via hydride abstraction followed by CO extrusion. It crystallized as an orange monoclinic compound with a = 10.4867(14), b = 14.843(3), c = 11.882(3) angstrom, beta = 94.057(15)-degrees. The cyclohexadienyl ligand is shown as boat conformation. A second bidentate complex was isolated. Spectroscopic and elemental analysis data support the demethylation product of [eta5-C5H4CH2CH2NH(CH3)Mo(CO)(eta3-C6H8)]+ PF6-.

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页码：155 / 162

页数：8

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