SKELETAL ISOMERIZATION OF 1-BUTENE ON 10-MEMBER RING ZEOLITE CATALYSTS

被引：95

作者：

OYOUNG, CL

PELLET, RJ

CASEY, DG

UGOLINI, JR

SAWICKI, RA

机构：

[1] Texaco, Inc., Beacon, NY 12508

来源：

JOURNAL OF CATALYSIS | 1995年 / 151卷 / 02期

关键词：

D O I：

10.1006/jcat.1995.1051

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Effects of zeolite pore structure on skeletal isomerization of 1-butenes are investigated. Three 10-member ring zeolites, ferrierite, ZSM-23, and ZSM-5, are studied and compared. Results show that ferrierite, with intersecting 10-MR and 8-MR channels, has better isomerization activity than ZSM-23, with monodirectional 10-MR channels, ZSM-5 with two intersecting 10-MR channels is not a selective isomerization catalyst. (C) 1995 Academic Press, Inc.

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页码：467 / 469

页数：3

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