VIBRATIONAL RAMAN-SPECTRUM AND FORCE-CONSTANTS OF PHOSPHORUS, P4

被引：21

作者：

EDWARDS, HGM

机构：

[1] Chemistry and Chemical Technology, University of Bradford, Bradford

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 295卷

关键词：

D O I：

10.1016/0022-2860(93)85009-J

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From the most precise experimental measurements available from the gas phase for the three vibrational wavenumbers of P4, the primary stretching force constant f(r) = 2.06 mdyn angstrom-1 and two stretch-stretch interaction constants have been evaluated using a simple valence force field. The positive value of f(rr), and negative value of f(rr) are confirmed and the value of f(r) is found to be significantly smaller (15% and 7%, respectively) than the corresponding values calculated from the infrared spectra of solutions of phosphorus in carbon disulphide reported in the literature.

引用

页码：95 / 100

页数：6

共 20 条

[1]

BEATTIE IR, 1970, J CHEM SOC A, P207

[2] THE VIBRATIONAL SPECTRA AND STRUCTURE OF INORGANIC MOLECULES .2. SULFUR S-8, SULFUR CHLORIDE S2CL2, PHOSPHORUS P-4 [J].