SYNTHESIS AND X-RAY STRUCTURAL-ANALYSIS OF [1-CARBONYL-1-(ETA-5-CYCLOPENTADIENYL-2, 3-DIMETHYL-1-TRIMETHYLPHOSPHINE-3-TRIMETHYLPHOSPHORANYLIDENE-1-TUNGSTA-2-THIACYCLOPROPANE]TETRAFLUOROBORATE

被引：22

作者：

SCHUTT, W ^{[1
]}

HERDTWECK, E ^{[1
]}

HAHN, F ^{[1
]}

KREISSL, FR ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80311-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dicarbonyl(eta5-cyclopentadienyl)[eta2-(methylthio)methylcarbene] tungsten tetrafluoroborate reacts with an excess of trimethylphosphine under carbonyl substitution and addition of trimethylphosphine at the carbene carbon to yield a 'wolframa-thiacyclopropane' complex with a trimethylphosphoranylidene unit. Synthesis, spectroscopic investigation and the X-ray structure are reported.

引用

页码：C33 / C36

页数：4

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