A NEW-TYPE OF PARATUNGSTATE

被引:33
作者
HARTL, H
PALM, R
FUCHS, J
机构
[1] Institut für Anorganische und Analytische Chemie, Freien Universität, Berlin, D-14195
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 10期
关键词
D O I
10.1002/anie.199314921
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For 65 years it has been discussed whether hexatungstate ions exist. Now the confirmation of their existence and the structural analysis of Na5[H3W6O22] · 18H2O have been achieved; in aqueous solution the latter is probably in equilibrium with the known [W7O24]6− ion. The polyhedral representa tion of the structure of [H3W6O22]5− is shown on the right. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
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页码:1492 / 1494
页数:3
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