TANDEM PUMMERER DIELS-ALDER SEQUENCE FOR THE PREPARATION OF ALPHA-THIO SUBSTITUTED NAPHTHALENE DERIVATIVES

被引：38

作者：

COCHRAN, JE ^{[1
]}

PADWA, A ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 20期

关键词：

D O I：

10.1016/0040-4039(95)00574-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha-thiocarbocation generated from the Pummerer reaction of an o-benzoyl substituted sulfoxide is intercepted by the adjacent keto group to produce an alpha-thio-isobenzofuran as a transient intermediate which undergoes a subsequent Diels-Alder cycloaddition with added dienophiles.

引用

页码：3495 / 3498

页数：4

共 17 条

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