RUTHENIUM(II) COMPLEXES WITH NEW TRIDENTATE LIGANDS CONTAINING P,N,O DONOR ATOMS - HIGHLY EFFICIENT CATALYSTS FOR TRANSFER HYDROGENATION OF KETONES BY PROPAN-2-OL

被引：135

作者：

YANG, H

ALVAREZ, M

LUGAN, N

MATHIEU, R

机构：

[1] UNIV TOULOUSE 2,CNRS,CHIM COORDINAT LAB,UPR 8241,F-31077 TOULOUSE,FRANCE

[2] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [RuCl2(PPh(3))(L)] in which L is a tridentate ligand with P, N and O-donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover less than or equal to 118800 h(-1)) in basic media; when L is optically active, no significant e.e. is observed.

引用

页码：1721 / 1722

页数：2

共 6 条

[1] SYNTHESIS AND EVALUATION OF THE BONDING PROPERTIES OF A POTENTIALLY TRIDENTATE LIGAND - 1-(DIPHENYLOPHOSPHINO)-2-ETHOXY-1-(2-PYRIDYL)ETHANE [J].