PREPARATION AND STRUCTURES OF THE NICKEL(II) AND SILVER(I) COMPLEXES OF A 17-MEMBERED DIBENZO MACROCYCLE WITH AN N2S3 DONOR SET

被引：16

作者：

KALLERT, U ^{[1
]}

MATTES, R ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ANORGAN CHEM,WILHELM KLEMM STR 8,W-4400 MUNSTER,GERMANY

来源：

POLYHEDRON | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1016/S0277-5387(00)83317-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nickel(II) and silver(I) complexes [Ni(L1)ClO4]ClO4 and [Ag(L1)]ClO4 Of the 17-membered dibenzo macrocyclic ligand L1 with an N2S3 donor atom set have been prepared and characterized by X-ray crystal structure determinations. Nickel(II) is octahedrally coordinated by the five donor atoms of L1 and a perchlorate oxygen atom. The overall symmetry of the [Ni(L1)]2+ Moiety is close to m symmetry. In [Ag(L1)]+, all five donor atoms of the ligand are bound to the metal ion. The coordination polyhedron is best described as a distorted pentagonal bipyramid. The conformation of this and of related ligands within their -HN-(CH2)2-X-(CH2)2-NH- fragments (X = O, N or S) will be discussed.

引用

页码：617 / 621

页数：5

共 13 条

[1] METAL-ION RECOGNITION .2. STRUCTURAL DISLOCATION BEHAVIOR IN THE INTERACTION OF ZINC(II) AND CADMIUM(II) WITH A SERIES OF O2N3-DONOR MACROCYCLES
ADAM, KR
DANCEY, KP
LEONG, AJ
LINDOY, LF
MCCOOL, BJ
MCPARTLIN, M
TASKER, PA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8471 - 8477
[2] NEW MACROCYCLIC LIGANDS SYNTHESIS OF AN EXTENSIVE SERIES OF POTENTIALLY PENTADENTATE LIGANDS CONTAINING MIXED NITROGEN, OXYGEN AND OR SULFUR HETEROATOMS - THE X-RAY STRUCTURE OF AN O2N2S DERIVATIVE
BALDWIN, D
DUCKWORTH, PA
ERICKSON, GR
LINDOY, LF
MCPARTLIN, M
MOCKLER, GM
MOODY, WE
TASKER, PA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (11) : 1861 - 1872
[3] SILVER MACROCYCLIC COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES AND REDOX PROPERTIES OF [AG([18]ANEN2S4)]PF6 AND [AG(ME2[18]ANEN2S4)]BPH4([18]ANEN2S4=1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE, ME2[18]ANEN2S4=7,16-DIMETHYL-1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE)
BLAKE, AJ
REID, G
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, : 615 - 620
[4] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES
Blake, Alexander J.
Schroeder, Martin
[J]. ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 : 1 - 80
[5] Cooper S.R., 1990, STRUCT BONDING BERLI, V72, P3
[6] BINDING OF THE LATE TRANSITION-METAL IONS TO THE MIXED N2S DONOR MACROCYCLIC LIGAND 1-THIA-4,7-DIAZACYCLONONANE (=L1) - X-RAY CRYSTAL-STRUCTURES OF [PTIV(L1)BR3]BR0.5CL0.5.2H2O, [AUIII(L1)CL2][AUCL4] AND [AG4(L1)4](CF3SO3)4
HEINZEL, U
MATTES, R
[J]. POLYHEDRON, 1991, 10 (01) : 19 - 25
[7] HENDRICK K, 1984, J AM CHEM SOC, V106, P1641
[8] HENDRIK K, 1985, PROGR INORG CHEM, V33, P1
[9] X-RAY CRYSTAL-STRUCTURES OF THE COPPER(II), NICKEL(II) AND SILVER(I) COMPLEXES OF A 17-MEMBERED DIBENZO MACROCYCLE WITH A N3S2 DONOR SET
KALLERT, U
MATTES, R
[J]. INORGANICA CHIMICA ACTA, 1991, 180 (02) : 263 - 269
[10] Lindoy LF., 1989, CHEM MACROCYCLIC LIG

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