(1,7-C2B10H10-1',3'-C6H4)3, A CYCLIC TRIMER FROM META-CARBORANEDIYL AND META-PHENYLENE UNITS - A NEW CATEGORY OF MACROCYCLE

被引：49

作者：

CLEGG, W ^{[1
]}

GILL, WR ^{[1
]}

MACBRIDE, JAH ^{[1
]}

WADE, K ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three icosahedral and three planar building blocks (C2B10 carboranes and benzene rings, respectively) alternate in the novel macrocycle 1. This contains a cavity that is surrounded by hydrogen atoms, of which six are bound to boron and three to carbon; this cavity thus offers potential guests an unusual environment. Such “cluster‐cycles” offer some scope for use as frameworks on which to hold bi‐ and trinuclear arrays of metal atoms. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1328 / 1329

页数：2

共 13 条

[1] POLYMERS AND CERAMICS BASED ON ICOSAHEDRAL CARBORANES - MODEL STUDIES OF THE FORMATION AND HYDROLYTIC STABILITY OF ARYL ETHER, KETONE, AMIDE AND BORANE LINKAGES BETWEEN CARBORANE UNITS
BROWN, DA
COLQUHOUN, HM
DANIELS, JA
MACBRIDE, JAH
STEPHENSON, IR
WADE, K
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (08) : 793 - 804
[2] COLQUHOUN HM, 1991, POLYM COMMUN, V32, P272
[3] COULT R, 1993, IN PRESS J ORGANOMET
[4] Diederich F, 1991, CYCLOPHANES
[5] Fox M. A., 1991, THESIS U DURHAM
[6] Gokel G. W., 1991, CROWN ETHERS CRYPTAN, V1
[7] Grimes R., 1982, METAL INTERACTIONS B
[8] GUTSCHE CD, 1989, CALIXERENES
[9] MACBRIDE JAH, UNPUB
[10] MUPRHY DM, 1993, J MATER CHEM, V3, P67

← 1 2 →