DERIVATOGRAPHIC INVESTIGATIONS OF POLYCARBONATES

被引：4

作者：

DOBKOWSKI, Z

RUDNIK, E

机构：

[1] Industrial Chemistry Research Institute, Warsaw

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1992年 / 38卷 / 09期

关键词：

KINETICS; POLYCARBONATES;

D O I：

10.1007/BF01979635

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Derivatographic non-isothermal investigations of the decomposition of PC in air provide useful information on the characteristic decomposition temperatures and the apparent activation energies of the observed steps of decomposition. The following sequence of apparent activation energies of the pyrolysis step was obtained: PC-M>PC-C>PC-A. The values of E for PC-M are the highest, due to shielding of the ester linkages by the ortho-methyl substituents.

引用

页码：2211 / 2219

页数：9

共 20 条

[1] VOLATILE COMBUSTION PRODUCTS OF POLYCARBONATE AND POLYSULFONE [J].

BALL, GL ;

BOETTNER, EA .

JOURNAL OF APPLIED POLYMER SCIENCE, 1972, 16 (04) :855-&

[2]

BORANOWSKA Z, 1970, POLIMERY, V15, P12

[3] THERMAL DEGRADATION OF POLYCARBONATE [J].

DAVIS, A ;

GOLDEN, JH .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (01) :45-&

[4]

FACTOR A, 1990, ACS SYM SER, V425, P274

[5]

FLYNN JH, 1990, POLYM POLYM CHARACTE, P637

[6] REACTION KINETICS IN DIFFERENTIAL THERMAL ANALYSIS [J].

KISSINGER, HE .

ANALYTICAL CHEMISTRY, 1957, 29 (11) :1702-1706

[7]

KRAJEWSKI B, 1971, POLIWEGLANY, P399

[8]

LEVANTOVSKAYA II, 1975, VYSOKOMOL SOEDIN A+, V17, P2331

[9]

LEVANTOVSKAYA II, 1968, VYSOKOMOL SOEDIN A, V10, P1633

[10]

MCCALLUM R, 1989, COMPREHENSIVE POLYM, V1, P903

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